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Star players earned wins in Quique Setien's first two games as Barcelona manager, but there was no rescue job during a limp defeat at Mestalla.
Quique Setien's honeymoon period as Barcelona coach is over after a Jordi Alba own goal and a strike from Maxi Gomez helped Valencia to a 2-0 win.
Real Madrid made short work of Valencia in the semifinal of the Spanish Super Cup, beating their fellow La Liga side 3-1 in Jeddah, Saudi Arabia.
Real Madrid will play Manchester City in the Champions League round of 16, and holders Liverpool will face Atletico Madrid.
Karim Benzema smashed the ball into the roof of the net in second-half stoppage time to give Real Madrid a 1-1 draw at Valencia in La Liga.
Ajax Amsterdam have been eliminated from the Champions League following their loss to Valencia on Tuesday.
Chelsea will have to wait to book their place in the Champions League round of 16 after a late goal earned Valencia a 2-2 draw.
Valencia breathed life into their hopes of qualifying for the Champions League round of 16 to come from behind to beat Lille 4-1.
Sevilla missed out on the chance to go level on points with La Liga leaders Barcelona as they were held to a 1-1 draw away to Valencia on Wednesday
Substitute Jonathan Ikone blasted home an equaliser deep into stoppage time to give Lille a 1-1 draw against 10-man Valencia.
Atletico Madrid's frustrating La Liga run continued as Dani Parejo's stunning late free kick earned Valencia a deserved 1-1 draw.
Valencia's problems all began with the Mestalla 15 years ago. From now until the end of the season, it will need to be their fortress.
Hakim Ziyech fired in an early goal, Quincy Promes added another and Donny van de Beek finished off a polished performance for Ajax.
Former Valencia president Juan Bautista Soler has been handed a two-year prison sentence for attempting to kidnap his successor, Vicente Soriano.
Troubled Valencia's joy at beating Chelsea in the Champions League in midweek was punctured by a disappointing 1-1 draw at home to Leganes.
Valencia are in chaos, again, following Marcelino sacking. Will victory at Chelsea be a turning point?
One of Spain's biggest but most dysfunctional clubs is in disarray again following the surprise sacking of the manager who'd fixed them.