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Ajax Amsterdam have been eliminated from the Champions League following their loss to Valencia on Tuesday.
Chelsea will have to wait to book their place in the Champions League round of 16 after a late goal earned Valencia a 2-2 draw.
Valencia breathed life into their hopes of qualifying for the Champions League round of 16 to come from behind to beat Lille 4-1.
Sevilla missed out on the chance to go level on points with La Liga leaders Barcelona as they were held to a 1-1 draw away to Valencia on Wednesday
Substitute Jonathan Ikone blasted home an equaliser deep into stoppage time to give Lille a 1-1 draw against 10-man Valencia.
Atletico Madrid's frustrating La Liga run continued as Dani Parejo's stunning late free kick earned Valencia a deserved 1-1 draw.
Valencia's problems all began with the Mestalla 15 years ago. From now until the end of the season, it will need to be their fortress.
Hakim Ziyech fired in an early goal, Quincy Promes added another and Donny van de Beek finished off a polished performance for Ajax.
Former Valencia president Juan Bautista Soler has been handed a two-year prison sentence for attempting to kidnap his successor, Vicente Soriano.
Troubled Valencia's joy at beating Chelsea in the Champions League in midweek was punctured by a disappointing 1-1 draw at home to Leganes.
Valencia are in chaos, again, following Marcelino sacking. Will victory at Chelsea be a turning point?
One of Spain's biggest but most dysfunctional clubs is in disarray again following the surprise sacking of the manager who'd fixed them.
Ross Barkley spurned a chance to equalise by missing a penalty three minutes from time as Chelsea lost to Valencia in the Champions League.
Valencia players are on a self-imposed silence heading into Tuesday's Champions League opener at Chelsea as a sign of protest.
Barcelona made short work of Valencia in a 5-2 win at the Camp Nou with an injured Lionel Messi looking on from the sidelines.
Marcelino has said he is "absolutely certain" that winning the Copa del Rey last season triggered his sacking as Valencia coach this week.
Marcelino has been sacked as Valencia coach with Albert Celades hired as a replacement, the Spanish La Liga club said on Wednesday.
Real Madrid will face Paris Saint-Germain in the Champions League group stage this season.
Barcelona have reached an agreement with Valencia on Thursday over the signing of Brazilian goalkeeper Neto for €26 million plus €9m in add-ons.
Barcelona have confirmed the sale of Andre Gomes to Everton for €25 million, while Jasper Cillessen is in Valencia ahead of a €30m transfer.
Andre Gomes and Jasper Cillessen are both set to complete moves away from Barcelona before the end of the week, sources have told ESPN FC.
Manchester United are in talks to sell Matteo Darmian, sources have told ESPN FC.